Physical and Chemical Properties of Alkyl Halides

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Physical and Chemical Properties of Alkyl Halides: Overview

This topic covers concepts such as physical properties of haloalkanes and haloarenes, colour of haloalkanes and haloarenes, chemical reactions of haloalkanes, reaction of haloalkanes with aqueous NaOH /aqueous NaOH, etc.

Important Questions on Physical and Chemical Properties of Alkyl Halides

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Which of the following combinations amongst the four Fischer projections represents the same absolute configurations?

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The compound with the above configuration is called:

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Which of the following sugars has the configuration (2S, 3R, 4R)?

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What kind of reagent would be needed to resolve a racemic amine, such as 2-aminobutane?

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The R/S configuration of these compounds are respectively.

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The R/S configuration of these compounds are respectively.

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A pure simple of 2-chlorobutane shows rotation of PPL by 30o in standard conditions. When above samples is made impure by mixing its opposite form, so that the composition of the mixture become 87.5 % d-form and 12.5 % l-form, then what will be the observed rotation for the mixture.

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Identify A, B, C and D in the following process :

(i)  CH3CH2ClNaCNANi/H2reductionB

(ii)  C6H5NH2NaNO2/HClCC6H5NH2/OHD 

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(CH3)3CMgCl on reaction with D2O produces –

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A solution of (+) -2-chloro-2-phenylethane in toluene racemises slowly in the presence of small amount of   SbC l 5 , due to the formation of –

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1–chlorobutane on reaction with alcoholic potash gives –

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n–Propyl bromide on treatment with ethanolic potassium hydroxide produces –

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The product of following reaction is –

C 2 H 5 O +C H 3 C H 2 I

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The alkyl halide on Wurtzs reaction gives an alkane with four primary, two secondary and two tertiary carbon atom is :-

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Match List-I with List-II.

1-Bromopropane is reacted with reagents in List-I to give product in List-II

  List-I Reagent   List-II Product
A. KOH (alc) I. Nitrile
B. KCN (alc) II. Ester
C. AgNO2 III. Alkene
D H3CCOOAg IV. Nitroalkane
Choose the correct answer from the options given below

 

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When methyl chloride is treated with ammonia and then treated with ethyl chloride for a long time. Find the end product.

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Write chemical reaction for the following conversion :

Ethyl bromide to ethene

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1,3-dibromo propane on reacting with Mg/dry ether forms _____. (Propene/ Cyclo propane)

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The following compounds are given to you:

(i). 2- Bromopentane

(ii). 2- Bromo -2- methyl butane

(iii).1- Bromopentane.

Which compound is most reactive towards elimination reaction and why ?